文章摘要
Study on Payne Effect and Mullins Effect of ZDMA Reinforced EVA/CPE/NBR TPV
  
DOI:
Key Words: ethylene-vinyl acetate copolymer;nitrile butadiene rubber;chlorinated polyethylene;zinc dimethacrylate;Payne effect;Mullins effect
Author NameAffiliation
LI Shuai Qingdao University of Science & Technology 
WEI Dong-ya Qingdao University of Science & Technology 
WANG Zhao-bo Qingdao University of Science & Technology 
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Abstract:
      Thermoplastic vulcanizate(TPV) of ethylene-vinyl acetate copolymer(EVA)/chlorinated polyethylene(CPE)/nitrile butadiene rubber(NBR) was prepared by dynamic vulcanization,and the stress-strain behavior,microstructure,Payne effect and Mullins effect of the obtained TPV were investigated.The zinc dimethacrylate (ZDMA) reinforced TPV showed a typical Payne effect: the storage modulus decreased obviously with the increase of strain amplitude.The ZDMA reinforced TPV also showed a strong Mullins effect.Under the same extension ratio,compared with those of unreinforced TPV,the maximum stress,instantaneous residual strain,internal loss,loss factor and softening factor of ZDMA reinforced TPV were higher.
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