文章摘要
Study on the characteristics of rare earth complex as rubber vulcanization accelerator
  
DOI:
Key Words: NR;SBR;rare earth complex;accelerator;curing characteristics;dynamic mechanical property
Author NameAffiliation
WEI Feng-xian South China Normal University 
ZHANG Wei-guang South China Normal University 
FAN Jun South China Normal University 
YIN Xia South China Normal University 
LIU Xian-feng South China University of Technology 
HUANG Miao-you South China University of Technology 
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Abstract:
      The N-cyclohexyl-2-benzothiazole sulfenamide neodymium complex was synthesized with accelerator CZ as ligand,and its application in NR/SBR blend was investigated.It was confirmed by element analysis and infra-red spectroscopy analysis that,the composition of the rare earth complex was Nd(CZ)Cl3·Nd(OH)Cl2·H2O. The rare earth complex had a delay characteristic of sulfonamide accelerators and was suitable for vulcanization of thick-walled rubber goods;after heat aging,the Shore A hardness,the modulus at 300% elongation and tear strength of vulcanizate were increased,the tensile strength,elongation at break and tensile set at break of vulcanizate were decreased;the rolling resistance and the heat build-up of tread compound with the rare earth complex could be decreased.
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