动态交联有机硅弹性体的研究进展 |
Research Progress of Dynamically Crosslinked Silicone Elastomers |
投稿时间:2024-04-18 修订日期:2024-04-18 |
DOI:10.12136/j.issn.1000-890X.2025.09.0712 |
中文关键词: 有机硅弹性体 聚硅氧烷 动态交联 非共价键 共价键 自修复 |
英文关键词: silicone elastomer polysiloxane dynamic crosslinking non-covalent bond covalent bond self-healing |
基金项目:国家自然科学基金NSAF基金重点资助项目(U2030203) |
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中文摘要: |
综述基于动态非共价键交联、动态共价键交联、多种动态键协同作用的有机硅弹性体的研究进展,展望动态交联有机硅弹性体的发展前景。在有机硅弹性体(聚硅氧烷)交联网络中引入多种动态交联键,既可以保持有机硅弹性体良好的理化性能,又为其提供了新的自修复途径和更好的可再加工性,动态共价键与非共价的协同作用成为有机硅弹性体实现优异力学性能和良好动力学行为的有效途径。动态交联有机硅弹性体的发展为其在智能涂料、传感器、柔性电子器件等领域的高值化应用和绿色化回收提供了新的方向。 |
英文摘要: |
Research progress of silicone elastomers based on dynamic non-covalent bond crosslinking,dynamic covalent bond crosslinking and multiple dynamic bond synergistic effect was reviewed,and the development prospect of dynamically crosslinked silicone elastomers was envisioned.By introducing multiple dynamic crosslinking bonds into the crosslinked network of silicone(polysiloxane),the good physicochemical properties of silicone elastomer were retained,while the novel self-healing pathways and better reprocessability were provided.The synergistic interaction between dynamic covalent bond and dynamic non-covalent bond was recognized as an effective way for achieving excellent mechanical properties and good dynamic behavior of silicone elastomer.The development of dynamically crosslinked silicone elastomers was regarded as a new direction for their high value application and environmentally friendly recycling in intelligent coatings,sensors and flexible electronic devices. |
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