| 气相色谱-质谱联用快速测定玩具及儿童用品中4种多环芳烃 |
| Rapid Determination of Four PAHs in Toys or Children’s Products by GC-MS |
| 投稿时间：2020-07-20 修订日期：2020-07-20 |
| DOI：10.12136/j.issn.1000-890X.2021.05.0380 |
| 中文关键词: 气相色谱-质谱 超声萃取 多环芳烃 玩具 儿童用品 |
| 英文关键词: GC-MS ultrasonic extraction PAHs toy children’s product |
| 基金项目:江苏省中小企业公共技术服务示范平台建设项目（2020-2023） |
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| 中文摘要: |
| 建立气相色谱-质谱联用快速测定玩具及儿童用品中苯并[c]芴、苯并[b]萘并[2，1-d]噻吩、5-甲基?和二苯并[cd，jk]芘4种多环芳烃的方法。结果表明，采用甲苯为萃取溶剂，超声波萃取50 min，采用DB-EUPAH毛细管色谱柱，选择离子监测模式下定量分析，可实现4种多环芳烃的有效分离。该方法的4种多环芳烃质量浓度测定线性范围为0.01～1 mg·L-1，线性相关因数不小于0.999 2，加标回收率为86.5%～108.7%，相对标准偏差小于3%，可用于玩具及儿童用品中4种多环芳烃的快速测定。 |
| 英文摘要: |
| A gas chromatography-mass spectrometry（GC-MS） method was established for the rapid determination of benzo（c）fluorene，benzo[b]naphtho[2，1-d]thiophene，5-methylphenanthroline and dibenzo[cd，jk]pyrene four polycyclic aromatic hydrocarbons（PAHs） in toys and children’s products.The results showed that using toluene as extraction solvent，ultrasonic extracting for 50 minutes，using DB-EUPAH capillary column，and selecting quantitative analysis in ion monitoring mode，four PAHs could be effective separated.The mass concentration testing linear range of four PAHs of this method was 0.01～1 mg·L-1，and linear correlation coefficient was not less than 0.999 2，the recovery rate was from 86.5% to 108.7%，and relative standard deviation was less than 3%.This method could be used for the rapid determination of four PAHs in toys and children’s products. |
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