| 结构调节剂双四氢糠丙烷对苯乙烯-异戊二烯橡胶微观结构的影响 |
| Effect of Structure Regulator DTHFP on Microstructure of SSIR |
| 投稿时间：2019-09-18 修订日期：2019-09-18 |
| DOI：10.12136/j.issn.1000-890X.2019.11.0803 |
| 中文关键词: 双四氢糠丙烷 结构调节剂 苯乙烯-异戊二烯橡胶 阴离子聚合 微观结构 |
| 英文关键词: DTHFP structure regulator SSIR anionic polymerization microstructure |
| 基金项目: |
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| 中文摘要: |
| 采用活性阴离子聚合方法，以环己烷为溶剂，正丁基锂（n-BuLi）为引发剂，选取新型结构调节剂双四氢糠丙烷
（DTHFP）（与传统的结构调节剂四氢呋喃和乙基四氢糠基醚进行比较）合成了苯乙烯（St）-异戊二烯（Ip）橡胶（简称戊
苯橡胶，SSIR），考察DTHFP用量、St/Ip质量比、聚合反应时间和反应温度对SSIR微观结构的影响。结果表明：随着结构
调节剂用量的增大，SSIR分子链中3，4-Ip结构含量均有所增大，3种结构调节剂中，DTHFP的调节能力最强，当DTHFP/
n-BuLi物质的量比为0.5时，3，4-Ip结构质量分数高达0.680 5；DTHFP可以提高St和Ip单体的聚合速率，且对St单体聚合
速率的调节能力更强；St/Ip质量比变化对Ip的微观结构影响不大；适当降低反应温度与增大DTHFP用量的效果相当。 |
| 英文摘要: |
| A styrene （St ）-isoprene （Ip ） rubber （SSIR） was synthesized by living anionic
polymerization using cyclohexane as solvent，n-butyllithium as initiator，and new structure regulator 2，2-di
（2-tetrahydrofuryl）propane（DTHFP），and DTHFP was compared with conventional structure regulators，
tetrahydrofuran and ethyl tetrahydrofurfuryl ether. The effects of the addition level of DTHFP，the weight
ratio of St/Ip，the reaction time and temperature on the microstructure of the SSIR were investigated. The
results showed that the content of 3，4-Ip structural units in SSIR increased with the increase of the addition
level of structural regulator. Among the three structure regulators，DTHFP had the strongest regulation
ability，and when the molar ratio of DTHFP/n-BuLi was at 0. 5，the mass fraction of 3，4-Ip structural
units reached as high as 0. 680 5. DTHFP could increase the polymerization rate of St and Ip monomer，and
the ability to adjust St monomer was stronger. The change of weight ratio of St/Ip had little effect on the
microstructure，and the effect of lowering the reaction temperature appropriately was equivalent to increasing
the addition level of DTHFP. |
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