文章摘要
含促进剂M与DM胶料的硫化特性
Vulcanization Behaviour of M or DM Containing Compounds
  
DOI:
中文关键词: 硫化  促进剂  硫化活化能
英文关键词: cure  accelerator  activation energy
基金项目:
作者单位
徐剑 江苏丹化集团公司化工助荆厂 
傅彦杰 化工部北京橡胶工业研究设计院 
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中文摘要:
      研究了促进剂M与DM在NR中的硫化特性,并深入探讨了它们对胶料加工性能及物性影响的差异。试验结果表明,促进剂M的焦烧速度、硫化速度比DM快,硫化平坦性比DM差,在较低温度下促进剂M对NR的增塑效果高于DM,但随着温度的升高,DM的增塑效果可超过M。促进剂M的活化能比DM低得多,说明其硫化速度对温度的依赖性小于DM。此外,含促进剂M胶料的拉伸强度、定伸应力、抗撕裂性、弹性等均略低于含DM的胶料,而耐热老化性能却比DM胶料好。
英文摘要:
      The vulcanization behaviour of M or DM containing NR compounds was studied and their effects on the processibility and physical properties were in detail respectively investigated.The results showed that the accelerator M gave more rapid scorch rate and cure rate,but worse cure plateau than the accelerator DM.The accelerator M gave larger plastication to NR than DM at lower temperature,but DM would give larger plastication than M as the temperature increased.The fact that the activation energy of M was much lower than that of DM implied less dependence of its cure rate on temperature than that of DM.In addition,the tensile strength,modulus,tear resistance and rebound resilience of M containing compound were somewhat lower than those of DM containing compound,but the former gave better heat-aging resistance than the latter.
Author NameAffiliation
Xu Jian Chemicals Factory of Jiangsu Danhua Group Corp. 
Fu Yanjie Beijing Research and Design Institute of Rubber Industry 
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