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高门尼粘度钕系顺丁橡胶/溶聚丁苯橡胶/天然橡胶胎面胶的性能研究
Properties of High Mooney Viscosity NdBR/SSBR/NR Tread Compound
Received:November 17, 2022  Revised:November 17, 2022
DOI:10.12135/j.issn.1006-8171.2024.01.0027
中文关键词: 门尼粘度;钕系顺丁橡胶;溶聚丁苯橡胶;天然橡胶;胎面胶;耐老化性能;抗切割性能
英文关键词: Mooney viscosity;NdBR;SSBR;NR;tread compound;aging resistance;cutting resistancegen aging property;wear resistance;dynamic mechanical property
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Author NameAffiliationE-mail
ZHAO Tianqi* Beijing Research and Design Institute of Rubber Industry Co.,Ltd zhaotianqiztq@163.com 
ZHOU Zhifeng Beijing Research and Design Institute of Rubber Industry Co.,Ltd  
ZHANG Zhiqiang CNPC Jinzhou Petrochemical Co.,Ltd  
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中文摘要:
      基于半钢子午线轮胎胎面胶配方,将两种高门尼粘度钕系顺丁橡胶(NdBR){记为NdBR-1#和NdBR-2#,门尼粘度[ML(1+4)100 ℃]分别为67和72,相对分子质量分布指数分别为3.26和2.31}与溶聚丁苯橡胶(SSBR)和天然橡胶(NR)并用,并与镍系顺丁橡胶(牌号BR9000)和NdBR(牌号CB22)作对比,研究高门尼粘度NdBR/SSBR/NR胎面胶的性能。结果表明:在BR/SSBR/NR三胶并用时,高门尼粘度NdBR的应用优势较明显;NdBR-2#胶料的综合性能优于NdBR-1#胶料,物理性能、滚动阻力及动态力学性能相当,抗裂口增长性能、抗切割性能和耐老化性能尤其突出,明显优于CB22胶料。NdBR-2#更适用于BR/SSBR/NR并用体系。
英文摘要:
      Based on the tread compound formula of steel-belted radial tire,two kinds of high Mooney viscosity neodymium butadiene rubber(NdBR,denoted as NdBR-1# and NdBR-2#,with Mooney viscosities of 67 and 72,and relative molecular mass distributions index of 3.26 and 2.31,respectively)were blended with solution polymerized styrene-butadiene rubber(SSBR) and natural rubber(NR),using nickel butadiene rubber BR9000 and NdBR CB22 as the comparison samples,the properties of high Mooney viscosity NdBR/SSBR/NR tread compounds were investigated.The results showed that,when BR/SSBR/NR were blended,high Mooney viscosity NdBR had obvious application advantage.The comprehensive properties of NdBR-2# compound were better than that of NdBR-1# compound,the physical properties,rolling resistance,and dynamic mechanical properties were comparable,in particular,the crack growth resistance,cutting resistance,and aging resistance were outstanding,obviously superior to that of CB22 compound.NdBR-2# was more suitable for the BR/SSBR/NR tread formulation system.
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