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| 不溶性硫黄对轮胎带束层胶料与镀铜钢丝帘线动态粘合性能的影响 |
| Effect of Insoluble Sulfur on Dynamic Adhesion Performance between Tire Belt Compound and Copper Plated Steel Cord |
| Received:August 24, 2022 Revised:August 24, 2022 |
| DOI：10.12135/j.issn.1006-8171.2024.02.0087 |
| 中文关键词: 不溶性硫黄；轮胎；带束层胶料；镀铜钢丝帘线；动态粘合性能 |
| 英文关键词: insoluble sulfur；tire；belt compound；copper plated steel cord；dynamic adhesion performance |
| 基金项目: |
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| Author Name | Affiliation | E-mail | | ZHANG Xin* | Shandong Yanggu Huatai Chemical Co.，Ltd；National Research Center of Rubber Additives Engineering Technology | 17862905259@163.com | | XU Xiaoping | Shandong Yanggu Huatai Chemical Co.，Ltd；National Research Center of Rubber Additives Engineering Technology | | | ZHAO Zhipeng | Shandong Yanggu Huatai Chemical Co.，Ltd；National Research Center of Rubber Additives Engineering Technology | | | LI Yunfeng | Shandong Yanggu Huatai Chemical Co.，Ltd；National Research Center of Rubber Additives Engineering Technology | | | YU Zhengzhou | Shandong Yanggu Huatai Chemical Co.，Ltd；National Research Center of Rubber Additives Engineering Technology | | | LIU Yushuai | Shandong Yanggu Huatai Chemical Co.，Ltd；National Research Center of Rubber Additives Engineering Technology | |
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| 中文摘要: |
| 研究不溶性硫黄对轮胎带束层胶料与镀铜钢丝帘线（简称镀铜钢丝）动态粘合性能的影响。结果表明：随着不溶性硫黄用量的增大，胶料的门尼焦烧时间t5逐渐缩短，t90－t10逐渐延长、门尼粘度、 FL.和Fmax逐渐增大；硫化胶的邵尔A型硬度增大，定伸应力增大，拉伸强度和拉断伸长率逐渐减小；静态和动态疲劳后胶料与镀铜钢丝的粘合抽出力均呈先增大后减小的趋势，抽出界面镀铜钢丝的裸露面积先减小后增大，覆胶体积先增大后减小。 |
| 英文摘要: |
| The effect of insoluble sulfur on the dynamic adhesion performance between tire belt compound and copper plated steel cord（referred to the copper plated steel） was studied.The results showed that as the amount of insoluble sulfur increased，the Mooney scorch time t5 of the compound gradually decreased，while ，t90－t10gradually prolonged，Mooney viscosity，FL. and Fmax gradually increased.The Shore A-type hardness of vulcanizate increased，the modulus increased，and the tensile strength and elongation at break gradually decreased.After static and dynamic fatigue，the adhesive extraction force between the compound and the copper plated steel showed a trend of first increasing and then decreasing，the exposed area of the copper plated steel at the extraction interface decreased at first，and then increased，and the adhesive volume increased at first，and then decreased. |
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