梁红文,任福君,吴小兵,张新军,张建国.充环保油溶聚丁苯橡胶的制备及在高性能轮胎胎面胶中的应用[J].轮胎工业,2012,(8):473-478 |
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充环保油溶聚丁苯橡胶的制备及在高性能轮胎胎面胶中的应用 |
Preparation of Solution Styrene Butadiene Rubber Filled with Environment-friendly Oil and Its Application in High Performance Tire Tread |
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DOI: |
中文关键词: 溶聚丁苯橡胶 环保油 乙烯基质量分数 物理性能 动态力学性能 |
英文关键词: solution styrene butadiene rubber environment-friendly oil vinyl mass fraction physical property dynamic property |
基金项目: |
中图分类号:TQ333.1;TQ333.2;TQ336.1+1 |
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中文摘要: |
以自制路易斯碱为调节剂(调节剂T)、正丁基锂为引发剂,采用阴离子聚合法、填充环保型芳烃油RAE制备环保型高乙烯基溶聚丁苯橡胶(HVSBR),并对比研究了几种胎面用丁苯橡胶与顺丁橡胶(BR)并用胶的性能。结果表明:少量的调节剂T有助于合成相对分子质量分布宽、加工性能好的HVSBR,乙烯基质量分数可达0.6~0.7;HVSBR/BR并用胶的综合物理性能、耐磨性能和动态力学性能较好,压缩疲劳温升和永久变形较小。 |
英文摘要: |
Using self-made Lewis base as modifier(modifier T) and n-butyllithium as initiator,the high-vinyl solution styrene butadiene rubber(HVSBR) was prepared by anionic solution copolymerization.HVSBR was filled with environment-friendly oil RAE, and the properties of several SBR/BR blends for tire tread were comparatively investigated.The results showed that,small addition level of modifier T helped to produce HVSBR with wide relative molecular weight distribution and good processability,and the mass fraction of vinyl content could reach 0.6~0.7.The comprehensive physical properties,wear resistance and dynamic properties of HVSBR/BR blend were better,and compression fatigue heat build-up and compression set were lower. |
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