优化配方设计提高9.00－20 16PR轮胎的综合性能

                                      徐志豪，亓秀红
                     ［莱芜市橡胶（集团）公司，山东 莱芜271100］

摘要：通过对900－20 16PR轮胎胎冠胶、缓冲层、胎肩胶和胎体帘布层内外层胶的配方优化，提高了轮胎的速度、耐久性能。胎冠胶采用NR/BR(50/50)并用、炭黑N234/N220并用(用量54份)；胎肩胶采用NR/BR(90/10)并用、硫化体系为促进剂NOBS、硫化剂DTDM和硫黄；缓冲胶采用全NR，炭黑N330/N660并用(用量44份)、硫化体系为促进剂CZ、不溶性硫黄与硫化剂DTDM；内外层胶采用NR/SBR/BR并用、炭黑N330/N660并用(用量40份)、硫化体系采用促进剂NOBS、DM、硫化剂DTDM和硫黄并用。改进后轮胎的速度性能达到110 km·h－1级运转1 h，耐久性能超过120 h。
关键词：载重斜交轮胎；配方设计；速度性能；耐久性能
中图分类号：U463341＋3；TQ3306+1文献标识码：B文章编号：10068171(2004)03014804

　

　

　

                      充油S-SBR加工行为的研究

                                         王雪，李伟，刘天鹤
                         (中石化股份有限公司北京燕山分公司 研究院，北京102500)

摘要：在中试装置上合成相对分子质量分布较宽的充油S-SBR，考察不同环烷油和芳烃油填充量的充油S-SBR的流变性能和混炼行为。结果表明，增大油的填充量能提高充油SSBR的流动性能，充芳烃油S-SBR相对于充环烷油的S-SBR对温度更敏感，宽相对分子质量分布的充环烷油S-SBR的混炼性能优于S-SBR1204及ESBR1778，宽相对分子质量分布的充芳烃油S-SBR的混炼性能优于SSBR1204，Solprene 380和ESBR1712。
关键词：S-SBR；充油胶；相对分子质量分布；流变性能；混炼行为
中图分类号：TQ333.1文献标识码：B文章编号：10068171(2004)03015204


作者简介：王雪（1978），男，河北衡水人，中石化股份有限公司北京燕山分公司研究院助理工程师，学士，主要从事新型弹性体材料的研究。


                          Study on processibility of oilextended SSBR

                                              WANG Xue,LI Wei,LIU Tianhe
            (Research Institute of Beijing Yanshan Petrochemical Co.,Ltd,Beijing102500,China)

Abstract:The various oilextended S-SBRs(OESSBR) with broader molecular weight distribution were synthesized on a pilot plant and the rheological properties and mixing behaviour of S-SBRs extended with different contents of naphthenic oil or aromatic oil were investigated.The results showed that the flowability of OESSBR improved by increassing the content of oil;the S-SBR extended with aromatic oil was more sensitive to the temperature than that extended with naphthenic oil;the mixing behaviour of naphthenic oilextended SSBR with broader MW was superior to those of SSBR1204 or ESBR1778;and the mixing behaviour of aromatic oilextended S-SBR was superior to those of SSBR1204,Solprene 380 and ESBR1712. 
Keywords:S-SBR;oilextended rubber;molecular weight distribution;rheological property;mixing behaviour

　

　

　

               烷基二硫代磷酸盐促进剂在NR胎面胶中的应用

                                             俞华英，罗映
                           （中橡集团 曙光橡胶工业研究设计院，广西 桂林541004）

摘要：研究烷基二硫代磷酸盐促进剂在NR胎面胶中的应用。应用烷基二硫代磷酸盐促进剂，可明显提高硫化胶的抗硫化返原性能，增大300%定伸应力，用量适宜时可降低脆性温度；通过调整硫化体系，使用05份烷基二硫代磷酸盐促进剂，可使胶料保持良好的焦烧安全性和耐屈挠龟裂性能。
关键词：烷基二硫代磷酸盐促进剂；NR；胎面胶；抗硫化返原性能
中图分类号：TQ33038+5；TQ3361文献标识码：B文章编号：10068171(2004)03015604


作者简介：俞华英（1956），女，浙江嘉兴人，中橡集团曙光橡胶工业研究设计院高级工程师，主要从事轮胎配方设计及生产工艺管理工作

　

　

                               Application of alkyl dithiophosphate accelerator
                                              in NR based tread compound

                                        YU Huaying,LUO Ying
                (Shuguang Research and Design Institute of Rubber Industry,Guilin541004,China)

Abstract:The application of alkyl dithiophosphate accelerator in NR based tread compound was investigated.The results showed that the antireversion of vulcanizate improved and the modulus at 300% also increased by using alkyl dithiophosphate accelerator,and the brittle temperature decreased by using the proper level of alkyl dithiophosphate accelerator;and the rubber compound with better scorch safety and flex crack resistance was obtained by using 0.5 phr of alkyl dithiophosphate accelerator and adjusting the curing system. 
Keywords:alkyl dithiophosphate accelerator;NR;tread compound;antireversion 

　

　

               分散剂FT-78在轮胎胎面胶中的应用

                           张必辉，吴学斌，程振华，王柱庆
                       （新疆昆仑股份有限公司，新疆 库尔勒841011）

摘要：研究分散剂FT78在轮胎胎面胶中的应用，并与胶易素T78进行对比试验。加入分散剂FT78的硫化胶物理性能与加入胶易素T78硫化胶相差不大，但耐磨性略优；加入分散剂FT78可以降低混炼能耗、缩短混炼周期；挤出胎面表面光滑、致密性好；可提高胎面胶成品的拉伸强度、撕裂强度和耐磨性；大大降低胶料成本。
关键词：分散剂；胎面胶；工艺性能；耐磨性
中图分类号：TQ33038+7；TQ3361文献标识码：B文章编号：10068171(2004)03016003


作者简介：张必辉（1957），男，重庆人，新疆昆仑股份有限公司高级工程师，主要从事轮胎结构设计及配方、生产工艺管理工作。

　

　

　

　

                促进剂TBSI在全钢载重子午线轮胎中的应用 
 
                                          何井武，安丰永，白俊霞
                                     （青岛双星轮胎工业公司，山东 胶南266400）

摘要：研究促进剂TBSI在全钢载重子午线轮胎上三角胶和胎体胶中的应用。在上三角胶配方中以促进剂TBSI等量替代促进剂NS，胶料的焦烧时间延长，硫化速度减慢，抗硫化返原性能提高，硫化胶的强伸性能及撕裂性能较优。在胎体胶配方中以1份促进剂TBSI替代125份促进剂DZ，胶料的焦烧时间延长，t90缩短，硫化胶的拉断永久变形减小，H抽出力相当。
关键词：促进剂；全钢载重子午线轮胎；上三角胶；胎体胶；H抽出力
中图分类号：TQ33038+5;U463341+6文献标识码：B文章编号：10068171(2004)03016303



作者简介：何井武（1971），男，黑龙江兰西人，青岛双星轮胎工业公司工程师，学士，主要从事子午线轮胎配方设计及技术管理工作。

                          Application of TBSI accelerator in BTR tire

                            HE Jingwu,AN Fengyong,BAI Junxia
                     (Qingdao Double Star Tire Company,Jiaonan266400,China)

Abstract:The application of TBSI accelerator in upper bead filler and carcass compounds of BTR tire was investigated.The results showed that the scorch time extended,the curing speed reduced,the antireversion improved,and the better tensile,elongation and tear properties were obtained using TBSI instead of TBBS by equal weight in the upper bead filler compound;and the scorch time extended,t90 reduced,the permanent tensile set decreased and the H pullout changed little using 1 phr of TBSI instead of 1.25 phr of DCBS in the carcass compound. 
Keywords:accelerator;BTR tire;upper bead filler;carcass compound;H pullout